Mertins O., Messina P., Labbé E., Arbault S., Lemaitre F., Buriez O., Amatore C.
Inorganica Chimica Acta 2011, 374(1), 59-68

Transport, reactivity and interactions of anti-tumor ferrocene-based compounds within lipid environments have been investigated electrochemically at a glassy carbon electrode (GCE) modified with a lipid bilayer film. Cyclic voltammetry performed in the presence of an adsorbed bilipid film in a H2O/EtOH (8/2) mixture, clearly showed that the affinity of the starting neutral ferrocifen derivatives towards the lipidic bilayer depends on both their size and their polarity. Likewise, the electrogenerated ferrocenium derivatives were expulsed reversibly from the bilayer in agreement with their positive charge. The reactivity of ferrocifen compounds was also investigated under the same conditions and in the presence of a base in order to trigger an intramolecular ferrocene-mediated (−2e −2H+) process within the lipidic film. Under these conditions, two distinct sequential electrochemical behaviors were observed depending on the base availability in the lipid layer, the magnitude of the corresponding two electrons wave being limited by the base concentration in the film. A full two-electron oxidation process, was observed as long as the amount of base present into the lipid layer was high enough to titrate the two protons released in the two-electron process. When this was sub-stoichiometric a second wave was observed at higher potential values representing the one electron oxidation of the ferrocifen excess.

2011-13

Thumbnail Dezest M., Bulteau A.L., Quinton D., Chavatte L., Le Béchec M., Arbault S., Salvayre A.N., Cousty S., Clément F. PLOS One, 2017, 12(3) Cold atmospheric pressure plasmas (CAPPs) are known to have...
Thumbnail C. Wattanakit, T. Yutthalekha, S. Asssavapanumat, V. Lapeyre, A. Kuhn Nature Comm. 2017, 8, 2087 see also CNRS press release Asymmetric synthesis of molecules is of crucial importance to obtain...
Thumbnail Giovanni Valenti, Sabina Scarabino, Bertrand Goudeau, Andreas Lesch, Milica Jovic, Elena Villani, Milica Sentic, Stefania Rapino, Stephane Arbault, Francesco Paolucci, and Neso Sojic J. Am. Chem....
Thumbnail V. Eßmann, S. Voci, G. Loget, N. Sojic, W. Schuhmann, A. Kuhn J. Phys. Chem. Lett. 2017,8, 4930–4934   Bipolar electrochemistry has been shown to enable and control various kinds of propulsion of...
Thumbnail Guangnan Meng, Vinothan N. Manoharan and Adeline Perro Soft Matter, 2017,13, 6293-6296 We design polystyrene–poly(N′-isopropylacrylamide-co-acrylic acid) core–shell particles that exhibit...
Thumbnail J. Gao, S. Chen, F. AlTal, S. Hu, L. Bouffier, G. Wantz.  ACS Appl. Mater. Interfaces, 2017, 9, 32405–32410.  A linear array of aluminum discs is deposited between the driving electrodes of an...
Thumbnail B. Gupta, B. Goudeau, A. Kuhn Angew.Chem. Int. Ed. 2017, 56, 14183-14186 see also Highlight in Chemistry Views and CNRS press release Electrochemical actuation of conducting polymers usually...
Thumbnail Z. Ali Fattah, L. Bouffier, A. Kuhn Applied Materials Today 2017, 9, 259–265, COVER Self-propelled micro/nanoswimmers performing directional motion are of great potential nowadays in the frame of...
Thumbnail T.D. Le, D. Lasseux, X.P. Nguyen, G. Vignoles, N. Mano, A. Kuhn Chemical Engineering Science 2017, 173, 153–167 A multi-scale model of diffusion/reaction at play in a porous electrode is developed...
Thumbnail M. Dabrowski, M. Cieplak, K. Noworyta, M. Heim, W. Adamkiewicz, A. Kuhn, P. S. Sharma, W. Kutner J. Mater. Chem. B, 2017,5, 6292-6299 Molecular imprinting in polymers leads, among others, to...
Thumbnail L. Bouffier, T. Doneux.  Current Opinion in Electrochemistry, DOI: 10.1016/j.coelec.2017.06.015. Electrochemistry and fluorescence microscopy are two complementary transduction techniques that offer synergetic...
Thumbnail G. Di Martino,V. A. Turek,  A. Lombardi, I.  Szabó, B. de Nijs,  A. Kuhn, E. Rosta, J.J. Baumberg Nano Lett. 2017, 17, 4840-4845 We study in real time the optical response of individual plasmonic...
Thumbnail Rémy Bois, Sabina Scarabino, Valérie Ravaine, Neso Sojic Langmuir, 2017, DOI: 10.1021/acs.langmuir.7b01585 We describe a method to confine electrochemiluminescence (ECL) at the oil-water interface of emulsion...
Thumbnail D. Zigah, O. Fontaine World Scientific, 2017, ISBN: 978-1-78634-353-6   Bioelectrochemical Systems (BESs) are innovative and sustainable devices. They combine biological and electrochemical...
Thumbnail C. Bodin,  E. Mourad,  D. Zigah,  S. Le Vot,  S. A Freunberger,  F. Favier, O. Fontaine Faraday Discuss., 2017,DOI: 10.1039/C7FD00174F   Nowadays, commercial supercapacitors are based on purely...
Thumbnail S. Tiewcharoen, C. Warakulwit, V. Lapeyre, P. Garrigue, L. Fourier, C. Elissalde, S. Buffière, P. Legros, M. Gayot, J. Limtrakul, A. Kuhn Angew.Chem.Int.Ed. (2017) 56, 11431-11435, COVER, HOT...
Thumbnail G. Di Martino, V. A. Turek,  C. Tserkezis, A. Lombardi, A. Kuhn, J.J. Baumberg Faraday Discuss., 2017, in press,doi 10.1039/C7FD00130D We study the optical response of individual nm-wide plasmonic...
Thumbnail A. G. Mark, E. Suraniti, J. Roche, H. Richter, A. Kuhn, N. Mano, P. Fischer Lab Chip, 2017, 17, 1761 HOT PAPER see also CNRS press release A variety of diagnostic and therapeutic medical...
Thumbnail I. Malytska, C. Mézière, M. Keilar, L. Hirsch, G. Wantz, N. Avarvari, A. Kuhn, L. Bouffier. Journal of Physical Chemistry C 2017, 121, 12921-12927.   Bipolar electrochemistry has recently emerged as a very...
Thumbnail L. Bouffier, S. Reculusa, V. Ravaine, A. Kuhn. ChemPhysChem 2017, 18, 2637-2642.   A new simple and versatile method for the preparation of surface wetting gradients is proposed. It is based on the...
Thumbnail C.A. Busatto, H. Labie, V. Lapeyre, R. Auzely-Velty, A. Perro, N. Casis, J. Luna, D.A. Estenoz, V. Ravaine Journal of Colloid and Interface Science, 493, 2017, 356–364. Polymer microgels have received...
Thumbnail L. Bouffier, N. Sojic, A. Kuhn Electrophoresis, 2017, 38, 2687-2694. A bipolar electrode is quite unconventional as it behaves simultaneously as an anode and a cathode in contrast to a classic...
Thumbnail M. Dabrowski, M. Cieplaka, P. Sindhu Sharma, P. Borowicz, K. Noworyta, W. Lisowski, F. D'Souza, A. Kuhn, W. Kutner Biosens.&Bioelectron.2017, 94, 155-161 Nanostructured artificial receptor...
Thumbnail Nenad R. Filipovic, Hana Elshaflu, Sonja Grubic, Ljiljana S. Jovanovic, Marko Rodic, Irena Novakovic, Aleksandar Malecevic, Ivana S. Djordjevic, Haidong Li, Neso Sojic, Aleksandar Marinkovic,...
Thumbnail Haidong Li, Silvia Voci, Antoine Wallabregue, Catherine Adam, Geraldine M. Labrador, Romain Duwald, Irene Hernández Delgado, Simon Pascal, Johann Bosson, Jérôme Lacour, Laurent BouffierNeso...