L. Zhang, C. Carucci, S. Reculusa, B. Goudeau, P. Lefrançois, S. Gounel, N. Mano, A. Kuhn

Chem Electro Chem 2019, 6, 4980-4984 (Cover).

The immobilization of bilirubin oxidase (BOD) on macroporous gold electrodes for the optimization of bioelectrocatalytic activity is described. A bilirubin oxidase mutant S362C (cys‐BOD) engineered with a cysteine residue located on purpose at the enzyme surface close to the T1 active center was used. It allows the attachment in one‐step of a self‐assembled monolayer of the enzyme to gold through a reaction between the thiol group of the cysteine residue and the metal surface. BOD immobilization of wild type and S362C mutant in macroporous gold electrodes allowed high retention of activity and perfect control of the overall BOD loading due to the fine‐tuning of the macroporous structure. The macroporous arrangement together with the use of cys‐BOD makes these rationally designed enzyme‐modified electrodes very promising candidates for high‐performance bioelectrocatalytic devices with improved activity and stability.

 

2019 12

Thumbnail J. Kalecki, M. Cieplak, M. Dąbrowski, W. Lisowski, A. Kuhn,  P. Sindhu Sharma ACS Sensors (2019) in press, doi.org/10.1021/acssensors.9b01878 Homogenous nanostructuration of molecularly imprinted...
Thumbnail C. Wattanakit, A. Kuhn Chemistry-A European Journal (2020) 26, 2993-3003 The concept of encoding molecular information in bulk metals has been proposed over the past decade. The structure of various types of...
Thumbnail S. Assavapanumat,  M. Ketkaew,  A. Kuhn, C.Wattanakit J. Am.Chem.Soc. 141 (2019) 18870(Front Cover) see also CNRS press release The enantioselective synthesis of chiral compounds is of crucial...
Thumbnail A. Bouchet-Spinelli, E. Descamps, J. Liu, A. Ismail, P. Pham, F. Chatelain, T. Leïchlé, L. Leroy, P. N. Marche, C. Raillon, A. Roget, Y. Roupioz, N. Sojic, A. Buhot, V. Haguet, T. Livache and P....
Thumbnail T.D. Le, L. Zhang, A. Kuhn, N. Mano, G. Vignoles, D. Lasseux J.Electroanal.Chem. (2019) in press Multiscale modelling of coupled diffusion and serial reduction reactions in porous micro-electrodes is...
Thumbnail S. Assavapanumat, M. Ketkaew, P. Garrigue, V Lapeyre, S Reculusa, C Wattanakit, A Kuhn ChemCatChem 11 (2019) 5951(Front Cover) Cover Profile Electrochemical water splitting is a crucially...
Thumbnail S. Assavapanumat, B. Gupta, G. Salinas, B. Goudeau, C. Wattanakit, A. Kuhn ChemComm 55 (2019) 10956 We report the synthesis of a hybrid bilayer, being composed of a free-standing conducting polymer...
Thumbnail A. Kuhn ChemPhysChem (2019) in press, DOI: 10.1002/cphc.201900932  Physical Chemistry is positioned at the interface of chemistry and physics and can be considered as a key player in modern science....
Thumbnail A. Dauphin, A. Akchach, S. Voci, A. Kuhn, G. Xu, L. BouffierN. Sojic J. Phys. Chem. Lett. 2019, 10, 318-5324 There is a very rapid development of original systems that can be remotely...
Thumbnail Y. Zhao, J. Yu, G. Xu, N. Sojic, G. Loget J. Am. Chem. Soc. 2019, 141, 13013−13016 We introduce the photo-induced electrochemiluminescence (P-ECL) of the model ECL system involving the...
Thumbnail L. Zhang, C. Carucci, S. Reculusa, B. Goudeau, P. Lefrançois, S. Gounel, N. Mano, A. Kuhn Chem Electro Chem2019,6, 4980-4984 (Cover). The immobilization of bilirubin oxidase (BOD) on macroporous gold...
Thumbnail A. Perro, L. Giraud, N. Coudon, S. Shanmugathasan, B. Goudeau, J.-P. Douliez and V. Ravaine Journal of Colloid and Interface Science2019 548, 275-283. Coacervation is a phase separation process...
Thumbnail M.-C. Tatry, E. Laurichesse, A. Perro, V. Ravaine and V. Schmitt Journal of Colloid and Interface Science2019, 548, 1-11. The aim of the paper is to examine the adsorption kinetics of soft...
Thumbnail S. Ramalingam, G. Le Bourdon, E. Pouget, A. Scalabre, J. Raghava Rao and A. Perro J. Phys. Chem B2019, 123 (7), 1708-1717. The design of nanocarriers containing hydrophobic and hydrophilic...
Thumbnail H. Labie, A. Perro, V. Lapeyre, B. Goudeau, B. Catargi, R. Auzély, V. Ravaine  Journal of Colloid and Interface Science 2019, 535, 16-27. A simple route to deliver on demand hydrosoluble molecules...
Thumbnail K. Vindas, L. Leroy, P. Garrigue, S. Voci, T. Livache, S. Arbault, N. Sojic, A. Buhot, E. Engel Anal. Bioanal. Chem., 2019. Remote detection by surface plasmon resonance (SPR) is demonstrated...
Thumbnail F. Zinna, S. Voci, L. Arrico, E. Brun, A. Homberg, L. Bouffier, T. Funaioli, J. Lacour, N. Sojic, L. Di Bari Angew. Chem. Int. Ed.,2019. The first observation of circular polarization of...
Thumbnail K. Mathwig, N. Sojic Journal of Analysis and Testing,2019, accepted. In ion-annihilation electrochemiluminescence (ECL), luminophore ions are generated by oxidation as well as reduction at electrodes...
Thumbnail J. Zhang, S. Arbault, N. Sojic, D. Jiang Annu. Rev. Anal. Chem. 2019. 12. Electrochemiluminescence (ECL) is a widely used analytical technique with the advantages of high sensitivity and low...
Thumbnail B. Gupta, M. C. Afonso, L. Zhang, C. Ayela, P. Garrigue, B. Goudeau, A. Kuhn ChemPhysChem 7 (2019) 941 (Cover) Combining the actuation of conducting polymers with additional functionalities is an...
Thumbnail M. Dąbrowski, A. Ziminska, J. Kalecki, M. Cieplak, W. Lisowski, R. Maksym, S. Shao, F. D’Souza, A. Kuhn, P. S. Sharma ACS Applied Materials and Interfaces 11 (2019) 9265 We present an improved...
Thumbnail I. Malytska, Th. Doneux, M. Bougouma, A. Kuhn, L. Bouffier. J. Phys. Chem. C, 2019, in press Doping of a transition-metal dichalcogenide deposited onto a conducting surface acting as bipolar...